By D. I. Edwards
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Additional resources for Antimicrobial Drug Action
E organism of a number of toxins which result in severe effects. Any useful antimicrobial drug acts best when the pathogen is actively growing and dividing, since it is at this stage that the organism is at its most sensitive. It follows that chemotherapy is most difficult when the organism is dormant or growing very slowly. Often these differences are reflected in the differing biochemistry of the organism. The most rapidly growing organisms are aerobic, generating a large amount of ATP for growth purposes.
1. 5 Biogenetic origin of penicillin G. 5 reveals thata-aminoadipate ~-AA) is not. incorporated into the penicillin molecule. 6, which also indicates the biosynthetic origins of cephalosporins. The key intermediate in penicillin synthesis is isopenicillin N which can either give rise to penicillin G and a variety of other penicillins if phenylacetate is replaced in the medium by other compounds, ora-aminoadipate is hydrolysed yielding 6-aminopenicillanic acid. This latter compound is an important starting point for the production of semisynthetic penicillins.
This is then subjected to successive methylation and chlorination after ring closure to form the two aromatic rings, oxidation leading to closure of the central ring and, finally, a stereospecific reduction of the 5-6 double bond to give griseofulvin. 3 Erythromycin The macrolides are in ill-defined group representing those antibiotics having large ring structures containing oxygen: the word macrolide is a contraction of macrocycliclactonide. Some authors apply the word to include the polyene antibiotics and others exclude them.